The demilitarisation of the Blackhawks prior to sale was a quote complex, time consuming and expensive process.I would suggest really thinking through the idea as a whole.
In a nutshell, you are proposing that Australia should gift Ukraine with troop transport helicopters that Australia has deemed not fit for purpose and has retired them early and is in the process of getting the replacement into service.
As I understand it, and as has been discussed on this thread previously, there seem to have been a few reasons why the ADF (and other armed forces) have decided to retire the MRH90 fleet. Some of those reasons involved their limited availability rates, maintenance demands, high cpfh and limitations/restrictions on operation.
Now also consider both Ukraine's helicopter lift needs are, what their CONOPS is or might be, as well as what their ability is to support and sustain a new type of helicopter in operations.
Lastly, consider what would likely need to be done to them in order to make them 'safe' in an Australian security context, for sale or gifting to the Ukraine, and then also have them delivered in a fit state to be used by Ukraine. I rather doubt that Australia might want to leave some of the more sensitive comms systems and/or EW/air defence countermeasures suites on board, as doing so could compromise existing ADF kit by revealing the capabilities (or lack thereof). Further, I would expect that any helicopters Ukraine would seek to operate would also need some decent decoy or self-defence suite systems due to the potential for being engaged by hostile GBAD and/or air systems.
Or to put it another way, Australia found that the MRH90 was not the right system for it, which means it likely is not the 'right' system for Ukraine either.
In fact of the Blackhawks, had they not already been disposed of, despite their greater age and higher hours I would not hesitate supplying them to Ukraine. For that matter nor would I hesitate supplying them Iroquois or Kiowas I'd we still had any.