I'm not santi but while we are awaiting for him, I'll try to answer some questions.
The Fire Scout was evaluated by the Spanish Navy in 2002 after Northrop Grumman sign on July of a technical assistance agreement with Izar (now Navantia) to integrate and promote the Fire Scout on the F-100 and F-310 classes.
The issue was the status of the project, some years would be needed to polish the design and demonstrate the real capacities of the RQ-8. Meanwhile the spanish government was pressing to to develop a "national" UAV, the initial results of the SIVA were less than... wondrous.
However, the UAV capability remained on the F-100 class and is an official request of the new BAM ships.
The space issue is also unclear. The exact dimensions for the Aussie F-100 remain to be seen. So, if we take the original hangar dimensions for the F-101, (15 m x 5,8 m x 5,6 m) the helo must be disembarked to store the UAVs. But IIRC the hangar was expanded or somewhat altered by Navantia after the construction of the F-101 but I not have the changed layout.
But like I said before, without a clear report of Navantia about the changes made to the F-100 for Australia, all of our assumptions may be wrong.
On the other hand, would be logical with the Navantia-Northrop Grumman agreement, that any F-100 (Koala version) would be prepared to operate and support the MQ-8B Fire Scout or the still undisclosed design desired by the Spanish Navy without problems.
The UAV question for the Spanish Armed forces is problematic and the favorite design of each service for the moment remains under wraps. The last year (June, 26) the Chief Admiral of the Spanish Navy (Zaragoza Soto) confessed that the Navy have a preferred design but with the imposition for a common UAV/UCAV for the three services (with naval capability required) forced to the Navy to wait to the Air Force & Army decision. And added to this the Zapatero's Government ordered four UAVs (Searcher Mk II) as interim solution, while all remain awaiting for the final decision of the EMaCon (Estado Mayor Conjunto) about the final model selected to be the UAV/UCAV for the Spanish Armed Forces.
Sorry for the novel... But I thought that would be illustrative.